PEI (Ultem) Complete Guide

PEI (Polyetherimide) / Ultem® Complete Guide Infographic

Also known as Ultem® — High-performance amorphous thermoplastic with excellent dimensional stability

What is PEI (Polyetherimide)?

Polyetherimide (PEI), best known under the brand name Ultem®, is an amorphous amber-transparent thermoplastic offering an excellent balance of mechanical, thermal, and electrical properties at a cost lower than PEEK or PAI.

PEI is supplied in extruded rod and sheet forms, as well as injection-molded granules. The natural grade is translucent amber, while glass-filled grades are opaque.

Key Properties of PEI

Property Value
Continuous Service Temperature 170°C
Glass Transition Temperature (Tg) 217°C
Tensile Strength 105 MPa (unfilled)
Tensile Modulus 3.5 GPa (unfilled), 6–9 GPa (GF30%)
Flammability UL94 V-0 (inherent — no additives)
Dielectric Strength 33 kV/mm
Water Absorption 0.25%

Advantages of PEI

  • High temperature resistance: 170°C continuous use, Tg of 217°C
  • Natural flame retardance: UL94 V-0 without additives — low smoke density
  • Excellent dimensional stability: Low CLTE, low creep even at elevated temperatures
  • Hydrolysis resistant: Withstands repeated steam sterilization
  • Good chemical resistance: Particularly to acids and chlorinated cleaners
  • Transparent: Amber-transparent in natural grade — unusual for a high-temperature plastic
  • Good machinability: Easier to machine than PEEK or PAI

Limitations of PEI

  • Contains BPA: Restricted for certain infant/children’s product applications
  • Notch-sensitive: Impact strength is lower than PC or PPSU — design requires careful attention to radii
  • Poor alkali resistance: Especially at elevated temperatures — avoid strong bases
  • Cost: More expensive than PC, PSU, and standard engineering plastics
  • Flow: Lower melt flow than standard plastics — requires higher processing temperatures

PEI vs PEEK: Choosing the Right Material

Factor PEI (Ultem) PEEK
Max Service Temp 170°C 260°C
Relative Cost Lower Higher
Chemical Resistance Good (acid-resistant) Superior
Transparency Yes (amber) No (opaque)
Flame Retardance Inherent V-0 V-0
Best Use Case Cost-sensitive high-temp applications Extreme environments

Available Grades

Unfilled PEI (Ultem 1000)

Baseline grade. Amber-transparent, good balance of properties for general high-temperature applications.

Glass Fiber Reinforced PEI (Ultem 2300 — 30% GF)

Higher stiffness and strength. Reduced elongation. Opaque. Ideal for structural components requiring dimensional stability.

Industry Applications

🛩️ Aerospace

Interior components, antenna housings, and ducting. PEI’s inherent flame retardance and low smoke density meet FAR 25.853 requirements.

🏥 Medical

Surgical instrument handles, sterilization trays, and medical device components that require repeated autoclave cycles.

⚡ Electronics

Coil formers, fuse housings, and connectors requiring high dielectric strength and thermal stability.

🍽️ Food Processing

Components requiring FDA compliance and resistance to acidic cleaning agents.

Machining Guidelines for PEI

  • Drying: 150°C for 3–4 hours recommended
  • Tooling: Standard carbide tools work well
  • Speeds: PEI machines cleanly at moderate speeds — produces crisp edges
  • Chip formation: Produces short, brittle chips — easy to manage
  • Annealing: 150–170°C for 2–4 hours for stress relief in precision parts

Frequently Asked Questions

Is PEI the same as Ultem?

Ultem® is SABIC’s brand name for PEI (polyetherimide). All Ultem grades are PEI. Other PEI brands are available from different manufacturers.

Can PEI be sterilized?

Yes. PEI withstands steam autoclaving (134°C), gamma radiation, and ethylene oxide (EtO) sterilization — making it popular for medical device applications.

Is PEI food safe?

Yes. PEI is FDA compliant for repeated food contact applications. However, due to BPA content, check specific regulations for infant/children’s food contact.

What is the difference between PEI and PEEK?

PEEK offers higher temperature resistance (260°C vs 170°C) and superior chemical resistance, but costs significantly more. PEI offers the best value in applications below 170°C.

JEKIN Polymer — Engineering-grade PEI (Ultem), PEEK, PAI, PPSU, PET, PVDF. Request a quote →

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